As Venky said , Pune has less quota and it will be better to book from LNL.
If its SL then still okay, but if u r trying for AC , then treat as if u are going for Tatkal. Go early at PRS Counter and try to remove the ticket in first 5 mins only.
I had very bad experience last month. I was booking via irctc site and after the payment, the ticket booking failed. I immediately booked second ticket, at around 8:10 am and got WL.
So...
more... be alert if u are going for AC.